A TEAM of Australian scientists has developed an atomic absorption spectrometer that creates an accurate international standard for temperature.
Published today in the journal Nature Communications, the researchers from the University of Adelaide, University of Queensland and University of Western Australia, have come up with a new way to determine Boltzmann’s constant, a number which relates the motion of individual atoms to their temperature.
The experiments contribute to a worldwide scientific effort in redefining the international unit of temperature: the kelvin. (Zero kelvin or ‘absolute zero’ is the absence of all thermal energy and equivalent to -273.15 degrees celsius).
“Although temperature is a familiar concept to all of us, remarkably it can only be measured accurately at a handful of locations around the globe,” says project leader, Professor Andre Luiten, Director of the University of Adelaide’s Institute for Photonics and Advanced Sensing (IPAS), where the experiments were conducted.
The spectrometer measured the speed of individual atoms moving in a gas by a factor of 16 times superior to anything previously demonstrated.
“An atom sitting at rest will absorb light of a particular frequency or colour ─ if it is moving towards you or away from you then the absorbed light is very slightly changed because of the Doppler effect,” says Professor Luiten. “This is exactly the same effect that makes a police siren sound different depending on whether the car is moving towards you or away. We use a pure laser to measure these changes in light absorption, from which we can infer the speeds of the atoms and the temperature of the gas.”
By conducting the experiments with world-record precision the team came across a completely unexpected effect. The light has an apparent effect on the atoms themselves: the measurement itself ends up changing the result. One of the breakthroughs of the project was to develop an explanation of how this happened and ensuring that it didn't affect the result.
The development means any laboratory in the world with appropriate skills and equipment could accurately measure temperature. Further development could deliver this capability to industry – something never before possible.
“Traditionally scientists kept a set of special clocks, rules and standard masses to define units such as the second, metre and kilogram,” says Associate Professor Tom Stace, from the ARC Centre for Engineered Quantum Systems at the University of Queensland. “Over the last 50 years we have been getting rid of these standards and replacing them with universal quantities such as the speed of light or the frequency at which certain atoms vibrate.
“This program is completed for time, electrical quantities and length but mass and temperature still make use of special objects. In the case of temperature, it is based on the freezing point of a very special type of water to define the kelvin which makes it difficult for all laboratories around the world to agree about temperature.
“Our work will bring a universally agreed temperature scale to the globe. As with any upgrade, this one will be deemed successful if people hardly notice the transition on a day-to-day basis. But for those at the cutting edge -- whether developing new metal alloys at very high temperatures, or measuring the temperatures of the coldest substances, the need for absolute temperature is critical.”
“When we started this research as an Australian Research Council Discovery Project in 2010, we decided to take a fundamentally different approach to measure temperature,” says Professor Eric May from the Centre for Energy at the University of Western Australia.
“The results show that taking a different approach clearly pays off ─ it has allowed us to observe and explain new phenomena.
“Creating agreed definitions of quantities is crucial for the industry and economy of all advanced technological societies.”